Scholarlink

<p>In this study, we investigated the performance of cesium lead halide perovskite solar cells through numerical simulations using a Solar Cell Capacitance Simulator (SCAPS). Three cell configurations are proposed: Yb/ZnO/CsPbI<sub>3</sub>/CuI/Au, Sm/TiO<sub>2</sub>/CsPbBr<sub>3</sub>/CuO<sub>2</sub>/Au, and Yb/TiO<sub>2</sub>/CsPbCl<sub>3</sub>/CuO<sub>2</sub>/Au. The solar cell was optimized by adjusting parameters such as the active layer thickness, hole transport layer (HTL), electron transport layer (ETL), metal work function (WF), defects, doping levels, series resistance (R<sub>S</sub>), and shunt resistance (R<sub>Sh</sub>). These studies indicate that photovoltaic performance is strongly influenced by critical factors, including the quality of the ETL and HTL layers, metal work function, series and shunt resistances, defect density, as well as the thickness and doping concentration of the absorber layers. The efficiencies of CsPbX<sub>3</sub> (X = I, Br, and Cl)-based perovskite solar cells were 26.68%, 16.76%, and 14.97%, respectively. The cells based on CsPbCl<sub>3</sub> and CsPbBr<sub>3</sub> exhibited superior stability, while the external quantum efficiency (EQE) measurements revealed that the CsPbI<sub>3</sub> cell responded across the entire visible and near-infrared spectrum, indicating its higher potential for photovoltaic applications compared to CsPbBr<sub>3</sub> and CsPbCl<sub>3</sub>. In conclusion, we found that for diffusion lengths (L) greater than ~ 600 nm, the reduction in the internal electric field in CsPbBr<sub>3</sub> and CsPbCl<sub>3</sub> cells promotes electron–hole recombination within the core layers.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Advancing solar cell efficiency: insights from cesium lead halide perovskite analysis

  • 期刊论文

  • 发表日期：

    2025年9月25日

查看全文
  • M. El-Mrabet,
  • A. Bouich,
  • A. Tarbi,
  • T. Chtouki,
  • H. Erguig,
  • A. Zawadzka,
  • A. Marjanowska,
  • A. Migalska-zalas,
  • A. Kityk,
  • A. Andrushchak,
  • G. Myronchuk,
  • B. Sahraoui

摘要

In this study, we investigated the performance of cesium lead halide perovskite solar cells through numerical simulations using a Solar Cell Capacitance Simulator (SCAPS). Three cell configurations are proposed: Yb/ZnO/CsPbI3/CuI/Au, Sm/TiO2/CsPbBr3/CuO2/Au, and Yb/TiO2/CsPbCl3/CuO2/Au. The solar cell was optimized by adjusting parameters such as the active layer thickness, hole transport layer (HTL), electron transport layer (ETL), metal work function (WF), defects, doping levels, series resistance (RS), and shunt resistance (RSh). These studies indicate that photovoltaic performance is strongly influenced by critical factors, including the quality of the ETL and HTL layers, metal work function, series and shunt resistances, defect density, as well as the thickness and doping concentration of the absorber layers. The efficiencies of CsPbX3 (X = I, Br, and Cl)-based perovskite solar cells were 26.68%, 16.76%, and 14.97%, respectively. The cells based on CsPbCl3 and CsPbBr3 exhibited superior stability, while the external quantum efficiency (EQE) measurements revealed that the CsPbI3 cell responded across the entire visible and near-infrared spectrum, indicating its higher potential for photovoltaic applications compared to CsPbBr3 and CsPbCl3. In conclusion, we found that for diffusion lengths (L) greater than ~ 600 nm, the reduction in the internal electric field in CsPbBr3 and CsPbCl3 cells promotes electron–hole recombination within the core layers.