Enhanced optoelectronic performance of Ni-incorporated ZnO nanoparticles on silicon substrates
摘要
This study investigates the elaboration of ZnO thin layers using a simple co-precipitation process, both in their pure form and with nickel (Ni) incorporation, followed by spin-coating onto silicon (Si) substrates. The research aims to evaluate how varying levels of Ni incorporation influence the films' structural, morphological, and opto-electronic properties. Analytical techniques including X-ray diffraction (XRD) and atomic force microscopy (AFM) were used to examine the surface morphology and crystal structure. To evaluate surface passivation and reflectivity and Fourier-transform infrared spectroscopy (FTIR) measurements were carried out on both Ni:ZnO and pure ZnO films. Significantly, Ni incorporation lead to in a substantial improvement of the lifetime values, from 2 μs to 82 μs at a carrier density of 1014 cm⁻3. Additionally, the reflectance at 500 nm was dramatically reduced starting 31% to around 5% upon coating Ni-incorporated ZnO on Si substrates.