<p>This study investigated the corrosion behaviors of Mg-9Al-1Zn (Al-modified alloy) and Mg-5Gd-4Y-1Zn (RE-modified alloy) from microstructural and electrochemical perspectives. The heterogeneous grain structure and dislocation distribution readily promoted galvanic corrosion, thereby accelerating the degradation of the RE-modified alloy. Furthermore, the potential difference induced by the LPSO phase was greater than that caused by the <i>β</i>-Mg<sub>17</sub>Al<sub>12</sub> phase, leading to a highly non-uniform overall potential distribution and the pronounced micro-galvanic corrosion in the RE-modified alloy. Notably, compared to modification by Gd<sub>2</sub>O<sub>3</sub>/Y<sub>2</sub>O<sub>3</sub>, the formation of Al<sub>2</sub>O<sub>3</sub>/Al(OH)<sub>3</sub> was more effective in enhancing the stability of the protective film. Consequently, the Al-modified alloy demonstrated superior corrosion resistance relative to the RE-modified alloy.</p>

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Microstructural and electrochemical perspective on corrosion resistance to understand why Mg-9Al-1Zn alloy outperforms Mg-5Gd-4Y-1Zn alloy

  • Xiangbin Li,
  • Dianfei Shao,
  • Jun Liang,
  • Yuxiu Zhang

摘要

This study investigated the corrosion behaviors of Mg-9Al-1Zn (Al-modified alloy) and Mg-5Gd-4Y-1Zn (RE-modified alloy) from microstructural and electrochemical perspectives. The heterogeneous grain structure and dislocation distribution readily promoted galvanic corrosion, thereby accelerating the degradation of the RE-modified alloy. Furthermore, the potential difference induced by the LPSO phase was greater than that caused by the β-Mg17Al12 phase, leading to a highly non-uniform overall potential distribution and the pronounced micro-galvanic corrosion in the RE-modified alloy. Notably, compared to modification by Gd2O3/Y2O3, the formation of Al2O3/Al(OH)3 was more effective in enhancing the stability of the protective film. Consequently, the Al-modified alloy demonstrated superior corrosion resistance relative to the RE-modified alloy.