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<p><i>Mastocarpus papillatus,</i> a red alga, has potential as a sustainable feedstock for the production of 5-hydroxymethylfurfural (5-HMF), a key bio-based chemical with applications in fuels and polymers. This study focuses on optimizing the hydrolysis conditions—temperature, reaction time, and ionic liquid (IL) concentration—to enhance the yield of 5-HMF. The optimal conditions for maximum 5-HMF production (5.92&#xa0;g L<sup>−1</sup>) were found to be 100&#xa0;°C, 60&#xa0;min of reaction time, and 3&#xa0;g of the ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl). The use of ionic liquids significantly improved sugar solubility and accelerated the hydrolysis process, enhancing the conversion efficiency. However, higher temperatures or prolonged reaction times led to the degradation of 5-HMF into unwanted by-products. These results demonstrate that <i>M. papillatus</i> is a promising and eco-friendly alternative to traditional biomass sources for the production of high-value chemicals, contributing to the development of green chemical processes.</p>

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Unlocking the potential of the red alga Mastocarpus papillatus as a sustainable source of 5-hydroxymethylfurfural (HMF)

  • 期刊论文

  • 发表日期：

    2026年2月7日

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  • Riri Uswatun Annifah,
  • Rossy Choerun Nissa,
  • Sukma Surya Kusumah,
  • Yurin Karunia Apsha Albaina Iasya,
  • Deddy Triyono Nugroho Adi,
  • Angela Martina,
  • Yeyen Nurhamiyah

摘要

Mastocarpus papillatus, a red alga, has potential as a sustainable feedstock for the production of 5-hydroxymethylfurfural (5-HMF), a key bio-based chemical with applications in fuels and polymers. This study focuses on optimizing the hydrolysis conditions—temperature, reaction time, and ionic liquid (IL) concentration—to enhance the yield of 5-HMF. The optimal conditions for maximum 5-HMF production (5.92 g L−1) were found to be 100 °C, 60 min of reaction time, and 3 g of the ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl). The use of ionic liquids significantly improved sugar solubility and accelerated the hydrolysis process, enhancing the conversion efficiency. However, higher temperatures or prolonged reaction times led to the degradation of 5-HMF into unwanted by-products. These results demonstrate that M. papillatus is a promising and eco-friendly alternative to traditional biomass sources for the production of high-value chemicals, contributing to the development of green chemical processes.