<p>Direct measurements of adiabatic temperature change (<InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10765_2025_3511_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="39" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta {{\varvec{T}}}_{{\varvec{S}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msub> <mrow> <mi mathvariant="bold-italic">T</mi> </mrow> <mrow> <mi mathvariant="bold-italic">S</mi> </mrow> </msub> </mrow> </math></EquationSource> </InlineEquation>) to characterize the barocaloric effect (σ<sub>b</sub>-CE) were a challenge and a point of interest for many research groups. In this work, we propose a device to measure <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="10765_2025_3511_Article_IEq2.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="39" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta {{\varvec{T}}}_{{\varvec{S}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msub> <mrow> <mi mathvariant="bold-italic">T</mi> </mrow> <mrow> <mi mathvariant="bold-italic">S</mi> </mrow> </msub> </mrow> </math></EquationSource> </InlineEquation> in a system with a simplified design and a new method to seal the pressure chamber. This new concept was tested for several materials in solid or liquid states. The methodology involves acquiring a temperature curve as a function of time under desired initial conditions. The results showed that the equipment can measure solid-state materials in powder, flakes, or solid bodies, in the absence or presence of a phase transition. When using coconut oil at high temperatures, for example, the apparatus remained sealed until the end of the experimental run. Promising values of σ<sub>b</sub>-CE, ranging from large to colossal, were captured for polymers, composites, first-order-transition materials, coconut oil, paraffin. This concept can inspire new research groups to develop equipment to study the barocaloric effect.</p>

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Device for Direct Barocaloric Measurement

  • Marcelo Augusto Yanes Moia,
  • Flavio Clareth Colman,
  • Gustavo Hannoun Giudai,
  • William Imamura,
  • Erik Oda Usuda,
  • Gabriel Fornazaro,
  • Laís Weber Aguiar,
  • Wagner André dos Santos Conceição,
  • Monica Ronobo Coutinho,
  • Silvia Luciana Favaro,
  • Cleber Santiago Alves,
  • Alexandre Magnus Gomes Carvalho,
  • Paulo Vinicius Trevizoli,
  • Jader Riso Barbosa Junior,
  • Rita de Cássia Colman Simões,
  • Eduardo Radovanovic,
  • Jean Rodrigo Bocca

摘要

Direct measurements of adiabatic temperature change ( \(\Delta {{\varvec{T}}}_{{\varvec{S}}}\) Δ T S ) to characterize the barocaloric effect (σb-CE) were a challenge and a point of interest for many research groups. In this work, we propose a device to measure \(\Delta {{\varvec{T}}}_{{\varvec{S}}}\) Δ T S in a system with a simplified design and a new method to seal the pressure chamber. This new concept was tested for several materials in solid or liquid states. The methodology involves acquiring a temperature curve as a function of time under desired initial conditions. The results showed that the equipment can measure solid-state materials in powder, flakes, or solid bodies, in the absence or presence of a phase transition. When using coconut oil at high temperatures, for example, the apparatus remained sealed until the end of the experimental run. Promising values of σb-CE, ranging from large to colossal, were captured for polymers, composites, first-order-transition materials, coconut oil, paraffin. This concept can inspire new research groups to develop equipment to study the barocaloric effect.