<p>Magnetic properties of NdNi<InlineEquation ID="IEq4"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation>P<InlineEquation ID="IEq5"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation> were investigated using <InlineEquation ID="IEq6"> <EquationSource Format="TEX">\(^{61}\)</EquationSource> </InlineEquation>Ni synchrotron-radiation-based Mössbauer spectroscopy. NdNi<InlineEquation ID="IEq7"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation>P<InlineEquation ID="IEq8"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation> is known to order ferromagnetically at <InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(T_{\mathrm C}=6.7~\textrm{K}\)</EquationSource> </InlineEquation> with the Nd moments along the <i>c</i>-axis. The <InlineEquation ID="IEq10"> <EquationSource Format="TEX">\(^{61}\)</EquationSource> </InlineEquation>Ni SR-based Mössbauer spectra show slight asymmetry due to the quadrupole interaction. The absence of any clear magnetic splitting confirms that Ni does not order magnetically. The spectrum below <InlineEquation ID="IEq11"> <EquationSource Format="TEX">\(T_{\mathrm C}\)</EquationSource> </InlineEquation> shows no significant broadening, suggesting that the transferred hyperfine magnetic field from the Nd moments at the Ni site is very small. Taken together with the magnetic measurements, these results suggest that the magnetism in NdNi<InlineEquation ID="IEq12"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation>P<InlineEquation ID="IEq13"> <EquationSource Format="TEX">\(_2\)</EquationSource> </InlineEquation> arises mainly from the RKKY interaction between Nd moments.</p>

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Magnetic properties and \(^{61}\)Ni synchrotron-radiation-based Mössbauer spectroscopy of NdNi\(_2\)P\(_2\)

  • Azumi Ishita,
  • Ryo Masuda,
  • Nobumoto Nagasawa,
  • Yoshitaka Yoda,
  • Satoshi Tsutsui,
  • Yoshio Kobayashi,
  • Jin Nakamura

摘要

Magnetic properties of NdNi \(_2\) P \(_2\) were investigated using \(^{61}\) Ni synchrotron-radiation-based Mössbauer spectroscopy. NdNi \(_2\) P \(_2\) is known to order ferromagnetically at \(T_{\mathrm C}=6.7~\textrm{K}\) with the Nd moments along the c-axis. The \(^{61}\) Ni SR-based Mössbauer spectra show slight asymmetry due to the quadrupole interaction. The absence of any clear magnetic splitting confirms that Ni does not order magnetically. The spectrum below \(T_{\mathrm C}\) shows no significant broadening, suggesting that the transferred hyperfine magnetic field from the Nd moments at the Ni site is very small. Taken together with the magnetic measurements, these results suggest that the magnetism in NdNi \(_2\) P \(_2\) arises mainly from the RKKY interaction between Nd moments.