Scholarlink

<p>The article examines a glass-forming region in the ternary TeO<sub>2</sub>–ZnO–MoO<sub>3</sub> system at two melt cooling rates. Glasses containing up to 80 mol.% molybdenum trioxide were obtained with varying TeO<sub>2</sub>/ZnO ratios. X-ray diffraction (XRD) was used to study the phase formation in the batch and glass samples under thermal treatment. No significant interaction between the initial binary oxides was observed in the temperature range of 20 – 300°C. However, further heating led to the formation of complex oxides of tellurium (IV), zinc, and molybdenum (VI), including Te<sub>2</sub>MoO<sub>7</sub>, Zn<sub>2</sub>Te<sub>3</sub>O<sub>8</sub>, ZnMoO<sub>4</sub>, and ZnTeMoO<sub>6</sub>. These phases were also formed during controlled glass crystallization. The transmission spectra of the glasses exhibited a redshift of the absorption edge with an increase in molybdenum trioxide content.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Glass Formation and Phase Transformations in the TeO2–ZnO–MoO3 System

  • 期刊论文

  • 发表日期：

    2025年5月15日

查看全文
  • O. A. Zamyatin,
  • Z. K. Nosov,
  • M. V. Krasnov

摘要

The article examines a glass-forming region in the ternary TeO2–ZnO–MoO3 system at two melt cooling rates. Glasses containing up to 80 mol.% molybdenum trioxide were obtained with varying TeO2/ZnO ratios. X-ray diffraction (XRD) was used to study the phase formation in the batch and glass samples under thermal treatment. No significant interaction between the initial binary oxides was observed in the temperature range of 20 – 300°C. However, further heating led to the formation of complex oxides of tellurium (IV), zinc, and molybdenum (VI), including Te2MoO7, Zn2Te3O8, ZnMoO4, and ZnTeMoO6. These phases were also formed during controlled glass crystallization. The transmission spectra of the glasses exhibited a redshift of the absorption edge with an increase in molybdenum trioxide content.