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<p>Three <i>Dracocephalum</i> (Lamiaceae) species growing in Russia, <i>D. argunense</i> Fisch. ex Rchb., <i>D. austriacum</i> L., and <i>D. peregrinum</i> L., were investigated and afforded 26 phenolic compounds, including four new flavonoids <b>1</b>–<b>4</b>. Compounds <b>1</b>–<b>4</b> were identified using UV and NMR spectroscopy and mass spectrometry as acacetin 7-<i>O</i>-(2″-<i>O</i>-sophorotriosyl)rutinoside (dracocephoside I, <b>1</b>), acacetin 7-<i>O</i>-(2″-<i>O</i>-sophorotriosyl)rutinoside 6‴-<i>O</i>-acetate (dracocephoside II, <b>2</b>), acacetin 7-<i>O</i>-(2″-<i>O</i>-sophorosyl)rutinoside 4‴-<i>O</i>-acetate (dracocephoside III, <b>3</b>), and acacetin 7-<i>O</i>-(2″-<i>O</i>-glucosyl)rutinoside 2‴-<i>O</i>-acetate (dracocephoside IV, <b>4</b>).</p>

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New Acacetin Glycosides from the Genus Dracocephalum

  • 期刊论文

  • 发表日期：

    2025年5月17日

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  • D. N. Olennikov,
  • G. Jafarova,
  • D. Isaev

摘要

Three Dracocephalum (Lamiaceae) species growing in Russia, D. argunense Fisch. ex Rchb., D. austriacum L., and D. peregrinum L., were investigated and afforded 26 phenolic compounds, including four new flavonoids 1–4. Compounds 1–4 were identified using UV and NMR spectroscopy and mass spectrometry as acacetin 7-O-(2″-O-sophorotriosyl)rutinoside (dracocephoside I, 1), acacetin 7-O-(2″-O-sophorotriosyl)rutinoside 6‴-O-acetate (dracocephoside II, 2), acacetin 7-O-(2″-O-sophorosyl)rutinoside 4‴-O-acetate (dracocephoside III, 3), and acacetin 7-O-(2″-O-glucosyl)rutinoside 2‴-O-acetate (dracocephoside IV, 4).