Characterization of teff straw fibers and optimization of soda-anthraquinone delignification of the teff straw for pulp production using response surface methodology in view of agricultural waste valorization
摘要
The aim of this research was to investigate the important features of teff straw fibers and its utilization in the pulp and paper industry through soda-anthraquinone pulping process. Morphological characterization indicated the average length of teff straw and the derived indices were comparable to the most non-wood plants and Eucalyptus. The chemical composition analysis of teff straw showed a cellulose content of 39.4%, hemicellulose of 29.6%, lignin of 14%, extractive of 7.2%, and ash content of 6.78. Response surface methodology with central Composite design was used to compare and optimize the effects of cooking temperature 130℃ to 150℃, cooking time 60 to 120 min, active alkali concentration 10 to 20% w/v and 0.20% w/w of anthraquinone based on oven dried teff straw. The responses evaluated were pulp yield and kappa number. The predicted optimized pulping results yielded 64.00% pulp (based on oven-dried teff straw) with a kappa number of 8.28. FTIR analysis confirmed the elimination of the non-cellulosic fiber compositions. The paper hand sheets of 60 g/m2 were prepared from the pulps produced at optimal conditions and tested for its mechanical properties showing breaking length of 4294 m, tensile strength of 11.6 kN/m, tensile index of 42.1 Nm/g, tear index of 5.2 mN.m2/g, burst index of 1.41 kPa.m2/g, and porosity of 19.5 se/100 air. The results indicated the tested morphological, chemical and strength properties were acceptable and made teff straw an alternative material for pulp and paper application.