Bio-derived Porous NiO Nanostructures for Multifunctional Electrochemical Applications: Glucose Sensing, Supercapacitive Energy Storage, and Water Splitting
摘要
The importance of multifunctional materials for various energy and biomedical applications is attracting the attention of scientists worldwide. In this study, Moringa-oleifera plant extract was used for the synthesis of highly porous NiO nanostructures. The confirmation of the successful formation of the nanostructures was done by XRD, FT-IR, FE-SEM, and BET analyses. A high surface area of 121.6 m2/g was shown by the synthesized NiO. The synthesized electrocatalyst was utilized as a sensor, supercapacitor electrode, and an electrode for HER and OER analyses. The sensing studies detected the presence of glucose upto 1 µM, which ensured the efficient activity of the material towards glucose oxidation. The supercapacitance studies ensured a higher specific capacitance of 623.4 F/g at a current density of 1 A/g. The efficacy of the synthesized NiO towards electrocatalytic water splitting was analyzed primarily through linear sweep voltametric studies. The HER studies showed a lower overpotential of 187 mV at a current density of 10 mA/cm2. The overpotential demonstrated by the material for OER at a current density of 5 mA/cm2 was 398 mV. The results confirmed the efficient multifunctionality of the Moringa-Oleifera plant extract aided synthesized NiO nanostructures.
Graphical Abstract