<p>The complete conversion of glycerol to gasoline was successfully carried out with the assistance of a beta zeolite catalyst synthesized via a solvent-free method. The synthesized beta zeolite exhibited well-developed porosity and strong acidic properties. Furthermore, the catalytic evaluation of the sample revealed a 100% glycerol conversion with a liquid product yield of 77.4%. Based on the carbon chain length, theliquid product showed full selectivity toward the gasoline range, yielding 77.4% gasoline product with an estimated research octane number (RON) of 104. Analysis of functional groups composition revealed the following distribution: Aromatics (32.7%) &gt; Olefins (29.2%) &gt; Isoparaffins (18.8%) &gt; Naphthenes (11.0%) &gt; Paraffins (8.3%). Furthermore, the study proposes the reaction mechanism for the catalytic conversion of glycerol into gasoline-range hydrocarbons.</p>

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Complete Conversion of Glycerol To Gasoline-Range Hydrocarbon Over Beta Zeolite Synthesized Via Solvent-Free Route

  • Faisal Aprialdi,
  • Didin Mujahidin,
  • Grandprix T. M. Kadja

摘要

The complete conversion of glycerol to gasoline was successfully carried out with the assistance of a beta zeolite catalyst synthesized via a solvent-free method. The synthesized beta zeolite exhibited well-developed porosity and strong acidic properties. Furthermore, the catalytic evaluation of the sample revealed a 100% glycerol conversion with a liquid product yield of 77.4%. Based on the carbon chain length, theliquid product showed full selectivity toward the gasoline range, yielding 77.4% gasoline product with an estimated research octane number (RON) of 104. Analysis of functional groups composition revealed the following distribution: Aromatics (32.7%) > Olefins (29.2%) > Isoparaffins (18.8%) > Naphthenes (11.0%) > Paraffins (8.3%). Furthermore, the study proposes the reaction mechanism for the catalytic conversion of glycerol into gasoline-range hydrocarbons.