<p>Spinel is a key mineral in magmatic systems, preserving signatures of their formation tectonic environments. However, processes like fluid-rock interactions and regional metamorphism can significantly alter their original chemical composition and microtexture. Chloritization is a process where primary spinel can react with surrounding silicates in the presence of H<sub>2</sub>O and SiO<sub>2</sub>-rich fluids in a reducing environment, leading to the formation of Cr- and Fe<sup>2+</sup>-rich ferrous chromite and pores filled with chlorite. While chloritization under reducing conditions is well known, its formation in oxidizing environments is undocumented. In the Archean Somnavandlapalli Ultramafic-Mafic (UM-M) Complex, disseminated Cr-spinels in ultramafic rocks are completely transformed with their primary composition erased, recording their chemical evolution in the progressive oxidizing environment. The Cr-spinel exhibit two distinct textures: clean (inclusion-free) and chloritized porous spinel with chlorite-filled cavities. Both display systematic zoning with core-rim texture, from a modified altered core with ferrian chromite (RIM-I) and Cr-magnetite (RIM-II) formed during progressive hydrothermal alteration under oxidizing conditions. Oxidation-induced chloritization and forming Fe<sup>3+</sup>-rich and Cr-depleted ferrian chromite (RIM-I) without ferrous chromite, followed by chlorite dissolution and magnetite precipitation, leads to the development of Cr-magnetite (Rim-II). Subsequent re-equilibration and homogenization resulted in the distinct zoning patterns in spinel grains. Final martitization converted magnetite to hematite, marking the terminal stage of the spinel alteration in a progressively oxidizing environment.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Textural fingerprints of Cr-Spinel in ultramafic rocks from the Somnavandlapalle Ultramafic-Mafic complex, Ramagiri greenstone belt, Andhra Pradesh, India: a case study of spinel alteration by progressive oxidation

  • Sukanya Chaudhury,
  • Sankhadeep Roy,
  • Lakshmi Mehera,
  • Rimpal Kar,
  • Prasun Ghosh,
  • Ankita Biswas,
  • Biswajit Ghosh

摘要

Spinel is a key mineral in magmatic systems, preserving signatures of their formation tectonic environments. However, processes like fluid-rock interactions and regional metamorphism can significantly alter their original chemical composition and microtexture. Chloritization is a process where primary spinel can react with surrounding silicates in the presence of H2O and SiO2-rich fluids in a reducing environment, leading to the formation of Cr- and Fe2+-rich ferrous chromite and pores filled with chlorite. While chloritization under reducing conditions is well known, its formation in oxidizing environments is undocumented. In the Archean Somnavandlapalli Ultramafic-Mafic (UM-M) Complex, disseminated Cr-spinels in ultramafic rocks are completely transformed with their primary composition erased, recording their chemical evolution in the progressive oxidizing environment. The Cr-spinel exhibit two distinct textures: clean (inclusion-free) and chloritized porous spinel with chlorite-filled cavities. Both display systematic zoning with core-rim texture, from a modified altered core with ferrian chromite (RIM-I) and Cr-magnetite (RIM-II) formed during progressive hydrothermal alteration under oxidizing conditions. Oxidation-induced chloritization and forming Fe3+-rich and Cr-depleted ferrian chromite (RIM-I) without ferrous chromite, followed by chlorite dissolution and magnetite precipitation, leads to the development of Cr-magnetite (Rim-II). Subsequent re-equilibration and homogenization resulted in the distinct zoning patterns in spinel grains. Final martitization converted magnetite to hematite, marking the terminal stage of the spinel alteration in a progressively oxidizing environment.