Scholarlink

<p> A&#xa0;surface-imprinted polymer SiO<sub>2</sub>@Eu(DBM)<sub>3</sub>phen/SMIP has been synthesized using enrofloxacin (ENFX) as the template molecule, methacrylic acid as the functional monomer, and the complex Eu(DBM)₃phen as a fluorescent moiety. The structure and the fluorescence sensing properties of SiO₂@Eu(DBM)₃phen/SMIP have been investigated in detail. The resulting material exhibited high selectivity, a low detection limit of 3.07&#xa0;µM, and a linear working range from 20 to 100&#xa0;µM for ENFX. The obtained fluorescence probe demonstrates good selectivity and sensitivity toward ENFX and has the potential for significant application in ENFX detection by simplifying procedures and reducing interference from impurities. In addition, the detection mechanism of the fluorescent probe was also discussed. The results indicate that it is feasible to use SiO<sub>2</sub>@Eu(DBM)<sub>3</sub>phen/SMIP for the detection of ENFX as well as its&#xa0;effective adsorption. This study explores the self-assembly of rare-earth complexes on silica via a surface imprinting technique, which provides a new solution for the subsequent development of the surface blotting technique.</p> Graphical Abstract <p></p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

A surface-imprinting lanthanide fluorescent hybrid probe on SiO2 microspheres for the detection of enrofloxacin

  • 期刊论文

  • 发表日期：

    2025年7月29日

查看全文
  • Xiao-Qing Huang,
  • Mao-Yu Wang,
  • Xiao-Chen Wang,
  • Xin Shi,
  • Rui-Wen Li,
  • Shuang Wu,
  • Ying Li

摘要

A surface-imprinted polymer SiO2@Eu(DBM)3phen/SMIP has been synthesized using enrofloxacin (ENFX) as the template molecule, methacrylic acid as the functional monomer, and the complex Eu(DBM)₃phen as a fluorescent moiety. The structure and the fluorescence sensing properties of SiO₂@Eu(DBM)₃phen/SMIP have been investigated in detail. The resulting material exhibited high selectivity, a low detection limit of 3.07 µM, and a linear working range from 20 to 100 µM for ENFX. The obtained fluorescence probe demonstrates good selectivity and sensitivity toward ENFX and has the potential for significant application in ENFX detection by simplifying procedures and reducing interference from impurities. In addition, the detection mechanism of the fluorescent probe was also discussed. The results indicate that it is feasible to use SiO2@Eu(DBM)3phen/SMIP for the detection of ENFX as well as its effective adsorption. This study explores the self-assembly of rare-earth complexes on silica via a surface imprinting technique, which provides a new solution for the subsequent development of the surface blotting technique.

Graphical Abstract