For two vertex-disjoint graphs H and F, let \(H \cup F\) denote their disjoint union and \(H + F\) their join. A \(W_4\) is defined as \(K_1 + C_4\) . In this paper, we establish improved bounds on the chromatic number of \((P_3 \cup P_2, W_4)\) -free graphs. We prove that for any such graph G, \(\chi (G) \le 2\omega (G)\) , which reduces the previous bound of \(3\omega (G)\) due to Wang and Zhang [2022]. This bound is shown to be tight for clique numbers \(\omega (G) \in \{2,3\}\) , as demonstrated by the Grőstzsch graph ( \(\omega =2, \chi =4\) ) and the complement of the Schla̋fli graph ( \(\omega =3, \chi =6\) ). Our result also generalizes several known bounds for subclasses of \((P_3 \cup P_2)\) -free graphs.