<p>The manipulation of quantum states via mechanical strain offers a pathway to engineer topological excitons in soft semiconductors. Here, we present a theoretical framework that shows that helical strain transforms lead halide perovskite quantum dots (QDs) into a platform for topological excitonics. Using a first-principles-informed framework combining strain-modulated Lamé eigenstates and non-perturbative Coulomb interactions, we identify a strain-driven topological transition at critical ellipticity <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(k = 0.59 \pm 0.02\)</EquationSource> </InlineEquation>, (corresponding to ≈ 2% torsional strain) marked by inversion of the exciton Chern number (<InlineEquation ID="IEq2"> <EquationSource Format="TEX">\(C = 0 \to 1\)</EquationSource> </InlineEquation>) and π-Berry phase accumulation. Quantitative calculations yield an exciton binding-energy enhancement up to 45&#xa0;meV and photoluminescence (PL) redshifts of ≈ 72&#xa0;meV, in agreement with experimental data. The computed deformation potential (− 0.8&#xa0;eV/% strain), group-velocity scaling (v ∝ k<sup>1.7</sup>), and Chern-number inversion confirm a strain-driven topological crossover supported by Berry-phase accumulation. Comparison with reported PL and diffusion measurements validates the predictive accuracy of the Lamé-Coulomb formalism, which bridges continuum elasticity with quantum confinement. These findings proposes perovskite QDs as experimentally accessible hosts of strain-tunable topological excitons, enabling reconfigurable quantum-photonic and optoelectronic devices based on mechanically programmable excitonic states.</p>

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Topological exciton dynamics in strain-engineered lead halide perovskite quantum dots

  • Moses Udoisoh,
  • Kabir Kehinde Adedeji,
  • Salihu Ahmad,
  • oluwatife Daniel Olaleye

摘要

The manipulation of quantum states via mechanical strain offers a pathway to engineer topological excitons in soft semiconductors. Here, we present a theoretical framework that shows that helical strain transforms lead halide perovskite quantum dots (QDs) into a platform for topological excitonics. Using a first-principles-informed framework combining strain-modulated Lamé eigenstates and non-perturbative Coulomb interactions, we identify a strain-driven topological transition at critical ellipticity \(k = 0.59 \pm 0.02\) , (corresponding to ≈ 2% torsional strain) marked by inversion of the exciton Chern number ( \(C = 0 \to 1\) ) and π-Berry phase accumulation. Quantitative calculations yield an exciton binding-energy enhancement up to 45 meV and photoluminescence (PL) redshifts of ≈ 72 meV, in agreement with experimental data. The computed deformation potential (− 0.8 eV/% strain), group-velocity scaling (v ∝ k1.7), and Chern-number inversion confirm a strain-driven topological crossover supported by Berry-phase accumulation. Comparison with reported PL and diffusion measurements validates the predictive accuracy of the Lamé-Coulomb formalism, which bridges continuum elasticity with quantum confinement. These findings proposes perovskite QDs as experimentally accessible hosts of strain-tunable topological excitons, enabling reconfigurable quantum-photonic and optoelectronic devices based on mechanically programmable excitonic states.