<p>Tunable magnetic material for absorbing microwave was achieved by developing zinc doped cobalt ferrite (Co<sub>1−δ</sub>Zn<sub>δ</sub>Fe<sub>2</sub>O<sub>4</sub>) to reflect its material magnetic property. Mechanical milling was used to make zinc-doped cobalt ferrite from stoichiometric Co<sub>3</sub>O<sub>4</sub>, ZnO, and Fe<sub>2</sub>O<sub>3</sub> raw materials. Morphology investigation using SEM demonstrates that particle sizes increase with Zn<sup>2+</sup> dopant ion composition. XRD pattern refinement shows all sample compositions are single phase. Peaks indexed to the Fd-3m space group in cubic symmetry resolved satisfactorily. It displayed a peak shift due to the Zn<sup>2+</sup> dopant ion, and Raman spectroscopy showed six active Raman vibration modes (2A<sub>1g</sub> + 3T<sub>2g</sub> + E<sub>g</sub>). The hysteresis curve of CoFe<sub>2</sub>O<sub>4</sub> doped with Zn<sup>2+</sup> ions show a decrease in ferrimagnetic behavior with Zn<sup>2+</sup> dopant. This decrease in ferrimagnetic behavior is influenced by the cationic distribution of Co<sup>2+</sup>, Zn<sup>2+</sup> and Fe<sup>3+</sup> ions in each tetrahedral and octahedral structure. Substitution of Zn<sup>2+</sup> ions with a composition of 0 ≤ δ ≤ 1 obtained saturation magnetization through the equation M = -73.143δ<sup>2</sup> − 7.2571<sup>δ</sup> + 85.757. While the coercivity field follows the relationship y = -1440δ<sup>3</sup> + 2668.6δ<sup>2</sup> − 1668.6δ + 438.57. Permittivity and permeability decrease with increasing concentration of Zn<sup>2+</sup> dopant ions. Two microwave absorption peaks in the X band indicate satisfactory functionality as a microwave absorber. The magnitude of RL<sub>max</sub> can be obtained through the relationship y = -29.867δ<sup>3</sup> + 49.6δ<sup>2</sup> − 22.933δ − 12.1.</p>

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Magnetic-dielectric loss response and tunable magnetic properties influencing microwave absorption in single-phase zinc-doped Cobalt ferrite

  • Yunasfi Yunasfi,
  • Jan Setiawan,
  • Mashadi,
  • Didin S. Winatapura,
  • Mustari,
  • Nanang Sudrajat,
  • Yana Taryana,
  • Dianta Ginting,
  • Guritno Gustianto,
  • M. P. Izaak,
  • Y. E. Gunanto,
  • Wisnu Ari Adi

摘要

Tunable magnetic material for absorbing microwave was achieved by developing zinc doped cobalt ferrite (Co1−δZnδFe2O4) to reflect its material magnetic property. Mechanical milling was used to make zinc-doped cobalt ferrite from stoichiometric Co3O4, ZnO, and Fe2O3 raw materials. Morphology investigation using SEM demonstrates that particle sizes increase with Zn2+ dopant ion composition. XRD pattern refinement shows all sample compositions are single phase. Peaks indexed to the Fd-3m space group in cubic symmetry resolved satisfactorily. It displayed a peak shift due to the Zn2+ dopant ion, and Raman spectroscopy showed six active Raman vibration modes (2A1g + 3T2g + Eg). The hysteresis curve of CoFe2O4 doped with Zn2+ ions show a decrease in ferrimagnetic behavior with Zn2+ dopant. This decrease in ferrimagnetic behavior is influenced by the cationic distribution of Co2+, Zn2+ and Fe3+ ions in each tetrahedral and octahedral structure. Substitution of Zn2+ ions with a composition of 0 ≤ δ ≤ 1 obtained saturation magnetization through the equation M = -73.143δ2 − 7.2571δ + 85.757. While the coercivity field follows the relationship y = -1440δ3 + 2668.6δ2 − 1668.6δ + 438.57. Permittivity and permeability decrease with increasing concentration of Zn2+ dopant ions. Two microwave absorption peaks in the X band indicate satisfactory functionality as a microwave absorber. The magnitude of RLmax can be obtained through the relationship y = -29.867δ3 + 49.6δ2 − 22.933δ − 12.1.