Parameterisation of interstitial iron-related defects in silicon wafers using injection-dependent lifetime spectroscopy
摘要
Injection-Dependent Lifetime Spectroscopy (IDLS) is used within this study for a parameterisation of interstitial iron Fei in p type Czochralski <100> silicon wafers. The first step is dedicated to study the presence of iron contamination using the crossover method for Fei and Iron-Bore pairs (Fe-B) dissociation, then the IDLS supported by the Defect Parameter Solution Surface (DPSS) are performed for the determination of capture coefficient σn/σp (σn, σp are the capture cross section for electrons and holes respectively) and the energy level in the band gap of Fei related defect (Et). The obtained parameters, σn/σp= 21 and Et= EV+0.38 eV, where Ev is the valence band energy, were used to fit the experimental Shockley–Read–Hall (SRH) lifetime provided by Quasi-Steady-State PhotoConductance measurement (QSSPC) to assess σn and σp. The objective of the second part of this work was to demonstrate the relationship between σn and the concentration of [Fei]. It is important to note that the electron-capture cross-section of Fei has been determined less accurately in the literature compared to the hole-capture cross-section and the energy level within the band gap Et. To validate the relationship between σn and the concentration of Fei, we assumed a value of 7×10-17 cm2 for σp and a value of EV+0.38 eV for energy level of trap Et, as reported in the literature. Subsequently, the value of σn was determined through the application of the equation K = σn/σp, which yielded a result of 21. The resulting parameters were then employed in the fitting of experimental data of the Shockley–Read–Hall lifetime (τsrh) versus injection level (∆n) [cm-3].