<p>This study investigates the effects of incorporating zinc oxide (ZnO) nanoparticles (1–5 mol%) into sodium borosilicate glasses containing a fixed amount of calcium fluoride (CaF<sub>2</sub>). The research aims to elucidate how ZnO modulates the structure and gamma radiation shielding ability of these glasses. Samples on the system (20-<i>x</i>)SiO<sub>2</sub>–25B<sub>2</sub>O<sub>3</sub>–14.5CaO–10CaF<sub>2</sub>–24.5Na<sub>2</sub>O–6P<sub>2</sub>O<sub>5</sub>–<i>x</i>ZnO, were prepared by the conventional melt-quenching technique and characterized using XRD, FTIR, Raman spectroscopy, and UV–Vis spectroscopy. The addition of ZnO was found to play a dual role as both a network former and modifier, creating Zn–O–Si linkages while also disrupting the silicate network. Notably, increasing ZnO content improved gamma radiation attenuation, as evidenced by increased attenuation coefficients and reduced half-value and tenth-value layer thicknesses. The study provides insights into optimizing borosilicate glass compositions for potential applications in bone tissue engineering and radiation shielding.</p>

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Structure and radiation shielding attitude of hexa-structured borosilicate glasses containing zinc oxide

  • E. Ahmed,
  • Hala M. Aly,
  • A. M. Abdelghany,
  • Abla A. Ismail

摘要

This study investigates the effects of incorporating zinc oxide (ZnO) nanoparticles (1–5 mol%) into sodium borosilicate glasses containing a fixed amount of calcium fluoride (CaF2). The research aims to elucidate how ZnO modulates the structure and gamma radiation shielding ability of these glasses. Samples on the system (20-x)SiO2–25B2O3–14.5CaO–10CaF2–24.5Na2O–6P2O5xZnO, were prepared by the conventional melt-quenching technique and characterized using XRD, FTIR, Raman spectroscopy, and UV–Vis spectroscopy. The addition of ZnO was found to play a dual role as both a network former and modifier, creating Zn–O–Si linkages while also disrupting the silicate network. Notably, increasing ZnO content improved gamma radiation attenuation, as evidenced by increased attenuation coefficients and reduced half-value and tenth-value layer thicknesses. The study provides insights into optimizing borosilicate glass compositions for potential applications in bone tissue engineering and radiation shielding.