Scholarlink

<p>Cyclotriveratrylene (CTV) possesses a rigid and bowl-shaped architecture with a <i>π</i>-electron-rich cavity. In this work, CTV modified with C10 alkyl chains (CTV-C10) has been synthesized and used for the first time as a stationary phase for gas chromatography (GC) analysis. The statically coated CTV-C10 column showed moderate polarity and high column efficiency (3446 plates m<sup>−1</sup>, determined by <i>n</i>-dodecane at 120&#xa0;°C). Due to its nanoscale channels, the CTV-C10 column displayed a strong affinity for aromatic compounds. Compared with CTV and commercial HP-5 and HP-35 columns, the CTV-C10 column exhibited better performance for the critical resolution of dibromobenzene, dichlorobenzene, and chloronitrobenzene isomers. Moreover, CTV-C10 columns showed 0.02%, 0.09%, and 4.96% repeatability RSD values for intra-day, inter-day, and between-columns, respectively. This study demonstrated the feasibility of CTV-C10 columns, providing a new perspective for developing selective nanoscale separation channels through CTV stationary phases in chromatographic analysis.</p> Graphical abstract <p></p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

A novel high-performance gas chromatographic stationary phase based on C10 alkyl-modified cyclotriveratrilene exploiting nanoscale separation channels

  • 期刊论文

  • 发表日期：

    2025年11月12日

查看全文
  • Tao Sun,
  • Xin Shen,
  • Xinyu Yang,
  • Haolong Qi,
  • Kexin Yang,
  • Yilin Xing,
  • Mengyi You,
  • Mengyao Duan,
  • Zhiqiang Cai,
  • Donatella Nardiello,
  • Maurizio Quinto,
  • Xianming Liu,
  • Shusheng Zhang

摘要

Cyclotriveratrylene (CTV) possesses a rigid and bowl-shaped architecture with a π-electron-rich cavity. In this work, CTV modified with C10 alkyl chains (CTV-C10) has been synthesized and used for the first time as a stationary phase for gas chromatography (GC) analysis. The statically coated CTV-C10 column showed moderate polarity and high column efficiency (3446 plates m−1, determined by n-dodecane at 120 °C). Due to its nanoscale channels, the CTV-C10 column displayed a strong affinity for aromatic compounds. Compared with CTV and commercial HP-5 and HP-35 columns, the CTV-C10 column exhibited better performance for the critical resolution of dibromobenzene, dichlorobenzene, and chloronitrobenzene isomers. Moreover, CTV-C10 columns showed 0.02%, 0.09%, and 4.96% repeatability RSD values for intra-day, inter-day, and between-columns, respectively. This study demonstrated the feasibility of CTV-C10 columns, providing a new perspective for developing selective nanoscale separation channels through CTV stationary phases in chromatographic analysis.

Graphical abstract