A portable gas pressure meter-based analytical kit for rapid analysis of S2− in water samples and food additives
摘要
Sulfide ions (S2−) are a hazardous pollutant present in our daily lives; thus, the accurate detection of S2− is critical for human health. However, conventional analytical methods have the disadvantage of high costs, complex operations, and the need for laboratory analysis. In this work, a miniaturized analytical kit was established for rapid analysis of S2− in water samples and food additives. In the presence of platinum nanoparticles (NPs), H2O2 was decomposed to O2 catalyzed by Pt NPs, resulting in a substantial increase in pressure inside the sealed reaction bottle. In the presence of S2-, S2− forms a Pt–S bond with Pt NPs and induces aggregation, thereby reducing the catalytic activity of Pt NPs, resulting in a decrease in O2 production and a corresponding decrease in gas pressure. Thus, the analysis of S2− was achieved by the measurement of gas pressure. S2− concentrations were inversely proportional to the gas pressures within a linear range of 0.2–5 μg/mL. A portable analytical kit was fabricated for rapid analysis of S2− in various samples, achieving recoveries of 90–109%, confirming its suitability as a potential analytical device for on-site environmental analysis and rapid food inspection.
Graphical Abstract