<p>With the growing use of biodegradable natural ester oils as green substitutes for mineral oils in transformers, this research is unique in exploring the compatibility with long-term thermal aging performance of room-temperature vulcanized (RTV) insulative silicone rubber soaked solely in natural ester oil. RTV silicone rubber, with its hydrophobicity, pollution flashover resistance, and hydrophobic recovery, is widely applied as a protective coating on transformer bushings. Nevertheless, its aging performance under exposure to natural ester oil over extended periods of time at higher temperatures is a relatively unexplored area. This study subjects RTV silicone rubber aged 320&#xa0;h at 40&#xa0;°C, 60&#xa0;°C, and 100&#xa0;°C to soybean-based natural ester oil to test. Results show oil absorption with mass gain of 5.45%, 15.82%, and 28.45% and surface roughness (<i>R</i><sub>a</sub>) of 0.11&#xa0;µm to 0.49&#xa0;µm. Contact angle decreased from 97.65° to 80.71° with aging, which shows loss of temporary hydrophobicity, with recovery seen within 100&#xa0;h. BDV decreased from 23&#xa0;kV (unaged) to 11&#xa0;kV (100&#xa0;°C-aged), showing loss of dielectric strength. Oil quality analysis contained up to 648.2&#xa0;ppm moisture, up to 0.47&#xa0;mg KOH/g TAN, and oil BDV as low as 36.5&#xa0;kV. This report hints at an emphasis on research work in future to achieve a greater thermo-electrical stability over the long run in RTV silicone rubber based in natural ester oil to suit transformer applications with increased lifetime and dynamic loads.</p>

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Assessing the impact of natural ester oil on RTV silicone rubber for transformer applications

  • S. Anula Beauty,
  • R. V. Maheswari

摘要

With the growing use of biodegradable natural ester oils as green substitutes for mineral oils in transformers, this research is unique in exploring the compatibility with long-term thermal aging performance of room-temperature vulcanized (RTV) insulative silicone rubber soaked solely in natural ester oil. RTV silicone rubber, with its hydrophobicity, pollution flashover resistance, and hydrophobic recovery, is widely applied as a protective coating on transformer bushings. Nevertheless, its aging performance under exposure to natural ester oil over extended periods of time at higher temperatures is a relatively unexplored area. This study subjects RTV silicone rubber aged 320 h at 40 °C, 60 °C, and 100 °C to soybean-based natural ester oil to test. Results show oil absorption with mass gain of 5.45%, 15.82%, and 28.45% and surface roughness (Ra) of 0.11 µm to 0.49 µm. Contact angle decreased from 97.65° to 80.71° with aging, which shows loss of temporary hydrophobicity, with recovery seen within 100 h. BDV decreased from 23 kV (unaged) to 11 kV (100 °C-aged), showing loss of dielectric strength. Oil quality analysis contained up to 648.2 ppm moisture, up to 0.47 mg KOH/g TAN, and oil BDV as low as 36.5 kV. This report hints at an emphasis on research work in future to achieve a greater thermo-electrical stability over the long run in RTV silicone rubber based in natural ester oil to suit transformer applications with increased lifetime and dynamic loads.