We formulate a collinear partonic shower algorithm that achieves next-to-single-logarithmic (NSL, \( {\alpha}_s^n{L}^{n-1} \) ) accuracy for collinear-sensitive non-singlet fragmentation observables. This entails the development of an algorithm for nesting triple-collinear splitting functions. It also involves the inclusion of the one-loop double-collinear corrections, through a z-dependent NLO-accurate effective 1 → 2 branching probability, using a formula that can be applied more generally also to future full showers with 1 → 3 splitting kernels. The specific NLO branching probability is calculated in two ways, one based on slicing, the other using a subtraction approach based on recent analytical calculations. We close with demonstrations of the shower’s accuracy for non-singlet partonic fragmentation functions and the energy spectrum of small-R quark jets. This work represents an important conceptual step towards general NNLL accuracy in parton showers.